Resonant X-ray Scattering and Crystal Structure Analyses

Electronic structure of Ni complexes by X-ray resonance Raman spectroscopy (resonant inelastic X-ray scattering).

The potential of 1s2p resonant inelastic (Raman) X-ray scattering (RIXS) is demonstrated for a series of Ni coordination complexes. In this technique, incident and scattered photon energies lie in the hard X-ray range (>5 keV). The 1s2p RIXS contour plots provide information that is complementary to K-edge and L-edge spectroscopy. RIXS spectroscopy promises to be a valuable probe of electronic ...

Resonant elastic soft x-ray scattering.

Resonant (elastic) soft x-ray scattering (RSXS) offers a unique element, site and valence specific probe to study spatial modulations of charge, spin and orbital degrees of freedom in solids on the nanoscopic length scale. It is not only used to investigate single-crystalline materials. This method also enables one to examine electronic ordering phenomena in thin films and to zoom into electron...

Magnetic Resonant Inelastic X-ray Scattering

X-Ray, Crystal Structure and Solution Phase Studies of a Polymeric SrII Compound

In the crystal structure of the title polymeric compound, [C42H38N6O33Sr5.2(H2O)]n, five independent metal atoms (Sr1-Sr5) have different coordination environments. The Sr1 and Sr5 atoms are nine coordinated and feature distorted tricapped trigonal-prismatic and capped square-antiprismatic geometries, respectively....

Resonant X-ray Scattering and Multiple Beam Diffraction in LaMnO3

Fig 1: The solid points give the location and shape of the (1 0 –4) resonant reflection in orthorhombic LaMnO3. Open circles display Mn Kα fluorescence from the same sample on a common energy scale. The vertical scale is arbitrary and the lines are guides to the eye. In conventional X-ray diffraction the beam scatters from all electrons in the unit cell, but in resonant diffraction at a forbidd...